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Oxidation of Magnesium with Dicarbonyl(cyclopentadienyl)iron(II) Chloride in Dimethylformamide
Authors:Maslennikov  S V  Piskunov  A V  Spirina  I V  Chekhonina  O Yu
Institution:(1) Research Institute of Chemistry, Lobachevskii Nizhni Novgorod State University, Nizhni Novgorod, Russia
Abstract:Oxidation of magnesium with dicarbonyl(cyclopentadienyl)iron(II) chloride in dimethylformamide gives rise to eegr5-C5H5Fe(CO)2MgCl. Kinetic regularities of the process were determined. Thermodynamic parameters of adsorption of the reagents on the metal surface were calculated.
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