Liquid-phase hydroformylation of 2,3- and 2,5-dihydrofurans |
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| Authors: | E Yu Vol'f T Yu Solov'eva M M Vartanyan L Yu Brezhnev A L Lapidus |
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| Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | The synthesis of 3-formyl derivatives of the tetrahydrofuran series was carried out by hydroformylation of 2,3-dihydrofuran and 2,5-dimethoxy-2,5-dihydrofuran in the presence of HRh(CO)(PPh3)3. The influence of the temperature, pressure, catalyst concentration, and the nature of the solvent on the conversion of dihydrofuran, the composition of aldehydes obtained and the selectivity of their formation was investigated.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2569–2571, November, 1989. |
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