Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins |
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| Authors: | Yoon Cheol Hwan Yoo Kyung Soo Yi Sung Wook Mishra Rajesh K Jung Kyung Woon |
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| Affiliation: | Department of Chemistry, University of South Florida (SCA 400), 4202 East Fowler Avenue, Tampa, Florida 33620, USA. |
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| Abstract: | [reaction: see text] Oxygen-promoted Pd(II) catalysis facilitated the synthesis of conjugated dienes by cross-coupling of alkenylboronic compounds and various olefins including highly substituted alkenes and cyclohexenone. Under mild conditions, these versatile reactions were efficient and highly stereoselective. |
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