Stereochemical Features of the Condensation of Lithiated (S)-N,N-Dimethyl-1-phenylethylamine with o-Methoxybenzophenones |
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Authors: | V. M. Dem’yanovich I. N. Shishkina Ya. A. Gritsyuk K. A. Potekhin A. V. Chesnova L. D. Ashkinadze |
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Affiliation: | (1) Faculty of Chemistry, Lomonosov Moscow State University, Vorob’evy gory 1, Moscow, 119899, Russia;(2) Vladimir State Pedagogical University, Vladimir, Russia |
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Abstract: | The condensation of lithiated (S)-N,N-dimethyl-1-phenylethylamine with o-methoxybenzophenones occurs in a nonstereoselective fashion due to possible coordination of lithium not only at the carbonyl group but also at the oxygen atom of the ortho-methoxy group.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 4, 2005, pp. 567–570.Original Russian Text Copyright © 2005 by Dem’yanovich, Shishkina, Gritsyuk, Potekhin, Chesnova, Ashkinadze. |
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