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One-dimensional polyoxometalate polymer constructed from V–W cluster by using asymmetrical bipyridine ligand |
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| Authors: | Zhangang Han Tao Chai Xueliang Zhai Jiye Wang Changwen Hu |
| Institution: | aCollege of Chemistry and Material Science, Hebei Normal University, Yuhua East Road 113, Shijiazhuang, Hebei 050016, China;bState Key Laboratory of Explosion Science and Technology, Institute for Chemical Physics, Department of Chemistry, Beijing Institute of Technology, Beijing 100081, China |
| Abstract: | The asymmetrical organic molecule 2,4′-bipyridine (bpy) is explored to assemble polyoxometalate into a one-dimensional hybrid and compound CuI(bpy)2]3CuI3(bpy)4]VVWVI9WV3O40] (1) is achieved. Compound 1 represents a V-centered Keggin VVWVI9WV3O40]6− cluster bonded together by incorporating secondary metal coordination group of Cu–bpy. The thermogravimetric analysis of 1 has also been researched. |
| Keywords: | Polyoxometalate Asymmetrical ligand Copper Polymer Supramolecular |
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