Hetero‐metallic Lanthanide CPs Involving Sodium: Synthesis,Crystal Structure,and Luminescence Properties |
| |
| Authors: | Zhi‐Wen Nie Sha‐Sha Li Cheng‐Hui Zeng Lei Wang Yuan Li Shun‐Gao Yin Sheng‐Liang Zhong |
| |
| Affiliation: | 1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, 330022 P. R. China;2. School of Chemistry and Chemical Engineering, Sun Yat‐Sen University, Guangzhou, 510275, P. R. China |
| |
| Abstract: | [TbNa(4‐msal)4(phen)2]n ( 1 ) (4‐msal = 4‐methyl salicylic acid), a new hetero‐metallic lanthanide coordination polymer (CP) involving sodium was synthesized. It crystallizes in the monoclinic space group P21/n, with a = 20.4809(9) Å, b = 9.8183(2) Å, c = 26.1987(11) Å, α = 90.00°, β = 112.922(5)°, γ = 90.00°, V = 4852.2(3) Å3, and Z = 4. The complex was characterized by single crystal and powder X‐ray diffraction, elemental analysis (EA), and Fourier transform infrared (FT‐IR) and luminescence spectroscopy. The luminescence properties of a powder sample of 1 were studied at room temperature and the luminescence lifetime and total quantum yield (QY) were determined. |
| |
| Keywords: | Lanthanide CPs Hetero‐metallic complexes Sodium Crystal structure Luminescence properties |
|
|
