Synthesis,X‐ray Studies,and Catalytic Efficacy of a Novel Iron Complex Containing an N,O‐Type Bidentate Thiazoline Ligand |
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Authors: | Mojtaba Amini Mina Bigdeli Sepideh Delsouz‐Hafshejani Arkady Ellern L. Keith Woo |
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Affiliation: | 1. Department of Chemistry, Faculty of Science, University of Maragheh, P.O. Box. 55181–83111, Maragheh, Iran;2. Chemistry Department, Iowa State University, Iowa 50011–3111, USA |
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Abstract: | The reactions of FeCl3 · 6H2O and 2‐(2′‐hydroxyphenyl)‐2‐thiazoline as a bidentate O‐N donor thiazoline ligand (thoz) afford a five‐coordinate FeIII complex [Fe(thoz)2Cl] with a distorted square pyramidal configuration. Complex [Fe(thoz)2Cl] was isolated as air‐stable crystalline solids and fully characterized, including by single‐crystal X‐ray structure analysis. Complex [Fe(thoz)2Cl] shows very efficient reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide (UHP) as the oxidant at room temperature in air. |
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Keywords: | Thiazoline Iron Crystal structure Sulfide oxidation |
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