A New Zinc(II) Coordination Polymer with a Threefold‐Interpenetrating Diamondoid Net: Synthesis,Crystal Structure and Luminescent Property |
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Authors: | Hui Miao Yumin Cui Feng Guo |
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Institution: | 1. College of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236041, P. R. China;2. Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong, Dezhou University, Shandong 253023, P. R. China |
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Abstract: | The three‐dimensional (3D) coordination polymer, Zn(dpa)(bib)]n ( 1 ) H2dap = diaphonic acid and bib = 1,4‐bis(imidazol‐1‐yl)benzene], was prepared by hydrothermal synthesis and characterized by single‐crystal X‐ray diffraction, FT‐IR spectroscopy, XRPD, and elemental analysis. Crystal structure determination revealed that complex 1 shows a threefold diamond topological net. Furthermore, the solid‐state luminescent property of Zn(dpa)(bib)]n was investigated. |
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Keywords: | Crystal structure Zinc Luminescence Diamondoid nets |
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