Synthesis and Characterization of a Zinc(II) Complex with Mixed 4‐Hydroxypyridine‐2,6‐dicarboxylic Acid and 1,3‐Bis(4‐pyridyl)propane Tectons |
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| Authors: | Yu‐Fang Wang Jun‐Qing Chen Jun‐Lei Geng |
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| Institution: | 1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, P. R. China;2. Student Management Office, Henan Industrial School, Zhengzhou, 450000, P. R. China |
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| Abstract: | The metal‐organic framework {Zn2(CAM)(μ2‐OH)(bpp)] · 2H2O}n ( 1 ) H3CAM = 4‐hydroxypyridine‐2,6‐dicarboxylic acid, bpp = 1,3‐bis(4‐pyridyl)propane], was hydrothermally synthesized and characterized by elemental analyses, infrared spectroscopy, and single‐crystal X‐ray diffraction. Compound 1 presents a three dimensional self‐penetrating 8‐connected framework with the Schläfli symbol 420.53.65. In addition, the fluorescent properties and thermal stability of 1 were discussed as well. |
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| Keywords: | Coordination polymers Zinc Fluorescence Thermal property |
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