Synthesis and Crystal Structure of an Adipate-bridged Dinuclear Cadmium(Ⅱ)Polymer with 2-Methylpyrazino[2,3-f][1,10]-phenanthroline(mpphen)Terminal Ligands |
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作者姓名: | CUI Yun-Cheng XU Yao-Yang HUANG Yan-Ju LIU Li-Hui LV Ming WANG Xiao-Mei WANG Jia-Jun |
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作者单位: | Chemistry Department of Jilin Normal University,Siping,Jilin 136000,China |
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基金项目: | This work was supported by Jilin Normal University. |
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摘 要: | <正>A metal-organic coordination polymer,Cd(C_(15)H_(10)N_4)(C_6H_8O_4)]_(2n)(1,C_(15)H_(10)N_4: 2-methyl-pyrazino-2,3-f]1,10]-phenanthroline(mpphen),C_6H_8O_4:adipate),was synthesized via hydrothermal synthesis.The polymer was characterized by elemental analysis,IR,TG and single-crystal X-ray diffraction.X-ray diffraction shows that 1 is a cadmium polymer constructed by adipate-bridged dinuclear clusters,and each adipate connects two clusters to form a two-dimensional planar structure.Crystal data for 1:monoclinic,space group C2/c,a=22.403(9),b= 16.039(6),c=13.808(6)(?),β=125.262(6)°,V=4051(3)(?)~3,M_r=502.79,D_c=1.649g/cm~3,μ(MoKα)=1.114 mm~(-1),F(000)=2016,Z=8,the final R=0.0509 and wR=0.1054 for 1509 observed reflections(I2σ(I)).
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关 键 词: | 水热合成法 镉(Ⅱ) 己二酸 晶体学 高分子结构 菲罗啉 配位聚合物 单晶X射线衍射 |
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