Influence of solvents on the molecular and crystal structure of the complex of 1,3-diallyl-5-[3-(diphenylphosphino)propyl]-1,3,5-triazine-2,4,6(1H,3H,5H)-trione with palladium(II) dichloride |
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| Authors: | I. P. Romanova A. T. Gubaidullin I. A. Litvinov S. G. Fattakhov V. S. Reznik O. G. Sinyashin |
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| Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation |
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| Abstract: | X-ray diffraction study demonstrated that the molecular and crystal structures of the complexes of 1,3-diallyl-5-[3-(diphenylphosphino)propyl]-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (1) with PdCl2 are determined to a large degree by intra- and intermolecular short contacts between different-polarity groups of the complex molecules. The strength and the existence of the complexes may be affected by the solvents from which the crystals are grown. Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1199–1204, July, 2000. |
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| Keywords: | X-ray diffraction analysis tertiary phosphine complexes with palladium(II) dichloride |
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