Reaction of vinylpyridines with oxazoles |
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Authors: | P. B. Terent'ev N. P. Lomakina M. Islam Rakhimi K. Dager Riad Ya. B. Zelikhover A. N. Kost |
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Affiliation: | (1) M. V. Lomonosov Moscow State University, 117234 Moscow;(2) Kabul Polytechnic Institute, Afghanistan |
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Abstract: | Depending on the structure, the reaction of the hydrochlorides of 2- and 4-vinylpyridines and 2-methyl-5-vinylpyridine with oxazoles leads to the synthesis of dipyridyls with or without a hydroxy group. It is shown that the regiospecificity of the reaction can be predicted on the basis of quantum-chemical calculations with the aid of the concepts of MO perturbation theory.Deceased.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1255–1262, September, 1980. |
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