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Reaction of vinylpyridines with oxazoles
Authors:P. B. Terent'ev  N. P. Lomakina  M. Islam Rakhimi  K. Dager Riad  Ya. B. Zelikhover  A. N. Kost
Affiliation:(1) M. V. Lomonosov Moscow State University, 117234 Moscow;(2) Kabul Polytechnic Institute, Afghanistan
Abstract:Depending on the structure, the reaction of the hydrochlorides of 2- and 4-vinylpyridines and 2-methyl-5-vinylpyridine with oxazoles leads to the synthesis of dipyridyls with or without a hydroxy group. It is shown that the regiospecificity of the reaction can be predicted on the basis of quantum-chemical calculations with the aid of the concepts of MO perturbation theory.Deceased.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1255–1262, September, 1980.
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