Molar heat capacities of some aqueous (2-amino-2-hydroxymethyl-1,3-propanediol + glycol) systems |
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| Institution: | 1. Departamento de Ingeniería Química,Universidad de Guanajuato, Noria Alta s/n Col. Noria Alta, Guanajuato, Guanajuato, 36050, México.;2. Departamento de Ingeniería de Procesos e Hidráulica, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340, México, D.F., México.;3. Coordinación de Ingeniería Bioquímica, Instituto Tecnológico Superior de Irapuato, Carretera Irapuato-Silao km 12.5. Col. El Colpal, Irapuato, Guanajuato, 36821, México.;4. Departamento de Ingeniería Química, Universidad Nacional de Colombia, Campus La Nubia, Bloque L, Manizales, Caldas, Colombia. |
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| Abstract: | A new set of molar heat capacity data for aqueous {2-amino-2-hydroxymethyl-1,3-propanediol (TRIS) + glycol} at (30 to 80) °C and different concentrations (4% to 16% by weight TRIS or 56% to 44% by weight water, in a fixed amount of glycol – 40% by weight) were gathered via reliable measurement method and are presented in this report. The glycols considered were diethylene glycol (DEG), triethylene glycol (TEG), tetraethylene glycol (T4EG), propylene glycol (PG), dipropylene glycol (DPG), and tripropylene glycol (TPG). The 198 data points gathered fit the equation, Cp = Cp,a + B1m + B2m2 + B3m3, where Cp and Cp,a are the molar heat capacities of the (TRIS + glycol + water) and (water + glycol) systems, respectively, Bi the temperature-dependent parameters, and m the mole TRIS per kilogram (glycol + water). The overall average absolute deviation (AAD) of the experimental data from the corresponding values calculated from the correlation equation was 0.07%. |
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