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Solubility of gases in fluoroorganic alcohols. Part II. Solubilities of noble gases in (water + 1,1,1,3,3,3-hexafluoropropan-2-ol) at 298.15 K and 101.33 kPa
Affiliation:1. University of Leuven (KU Leuven), Department for Pharmaceutical and Pharmacological Sciences, Pharmaceutical Analysis, Herestraat 49, 3000 Leuven, Belgium;2. Vrije Universiteit Brussel, Department of Computer Science, Artificial Intelligence Lab, Pleinlaan 9, 1050 Brussel, Belgium;3. Vrije Universiteit Brussel, Department of Chemical Engineering, Pleinlaan 2, 1050 Brussel, Belgium
Abstract:Solubilities of noble gases He, Ne, Ar, Kr and Xe in mixtures of {water + 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP)} at 298.15 K and 101.33 kPa partial pressure of gas are reported. A polynomial dependence of the solubilities on the mole fraction of the binary liquid mixture is found. The Henry’s constants at the vapor pressure of the mixture, the standard changes in the Gibbs free energy for the solution process and for the solvation process, and the so-called excess Henry’s constant are calculated. The results have been compared with those obtained by scaled particle theory (SPT).
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