The photoelectron spectra of tricyclo[3.3.0.02,6]Octene and tricyclo[3.3.0.02,6]Octane |
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| Authors: | P Bischof R Gleiter MJ Kukla LA Paquette |
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| Institution: | Institut für Organische Chemie der Technischen Hochschule, D 61 Darmstadt B.R.D.;Dept. of Chemistry, The Ohio State University, Columbus, Ohio 43210 U.S.A. |
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| Abstract: | The photoelectron spectra of tricyclo3.3.0.02,6]octene (1) and tricyclo3.3.0.02,6]octane (2) have been recorded. The first bands in these spectra are correlated with orbitals which are linear combinations of the Walsh orbitals and of the olefinic π-orbital. This assignment is based on a zero differential overlap molecular orbital model as well as on the results of extended Hückel calculations. The resonance integral <π|H|W > for 1 is found to be ?1.34 eV. |
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