Electron impact spectra of some alkyl derivatives of water and related compounds |
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Authors: | Wing-Cheung Tam CE Brion |
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Institution: | Department of Chemistry, University of British Columbia, Vancouver 8, B.C. Canada |
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Abstract: | Electron impact energy loss spectra at impact energies of 100 eV and 50 eV and a scattering angle of 2 degrees are presented for alkyl derivatives of H2O and related compounds. Spectra of H2O, CH3OH, CH3OCH3, ethylene oxide, CH3CH2OH, (CH3)2CHOH, (CH3)3C C2H5OC2H5 and tetrahydrofuran are tentatively assigned using derived term values and ionization potentials from photoelectron spectrosc Substituent effects on Rydberg orbital energies are discussed using Taft σ* values. |
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