辛硫磷和氯氰菊酯的大口径毛细管气相色谱定量分析研究

 对辛硫磷和氯氰菊酯的复配农药——２０％辛氯乳油进行了气相色谱定量分析的研究。以甲基对硫磷为内标,使用大口径毛细管柱,采用快速程序升温、高载气流速等手段,解决了辛硫磷高温易分解与氯氰菊酯色谱流出温度高的矛盾。在相同的色谱条件下对二者进行定量分析,变异系数分别为０．６７％和１．０％。方法简便、快速、准确。

Quantitative analysis of phoxim and cypermethrin using wide bore capillary column gas chromatography]

A compound pesticide, 20% P-C emulsion, consisting of 18.5% phoxim and 1.5% cypermethrin pesticides and other accessory agents is especially effective in controlling and killing boll worms. For its quality control some difficulties were encountered. In this paper we propose a simple and practical method for GC analysis of the product by use of a short wide bore capillary column (HP-1, 5m x 0.53mm x 2.65microm), high carrier gas flow rate and high-speed temperature programming etc.. Content analysis of efficient composition of "20% P-C emulsion" was completed under the chromatographic conditions using methyl parathion as an internal standard. Coefficient of variation of phoxim and cypermethrin were 0.67% and 1.0% respectively.