On the role of intermolecular interactions on structural and spin-crossover properties of 2D coordination networks [Fe(bbtr)3]A2 (bbtr=1,4-bis(1,2,3-triazol-1-yl)butane; A=ClO4(-), BF4(-)) |
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| Authors: | Kusz Joachim Bronisz Robert Zubko Maciej Bednarek Gabriela |
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| Institution: | Institute of Physics, University of Silesia, Katowice, Poland. |
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| Abstract: | A series of complexes M(bbtr)3]A2 (M=FeII, ZnII; bbtr=1,4‐bis(1,2,3‐triazol‐1‐yl)butane; A=ClO4?, BF4?) and FexZn1?x(bbtr)3](ClO4)2 (0<x<1) dilute systems was synthesized and characterized. Earlier studies on Fe(bbtr)3](ClO4)2 ( 1?ClO4 ), which crystallizes in space group P$\bar 3A series of complexes M(bbtr)(3)]A(2) (M=Fe(II), Zn(II); bbtr=1,4-bis(1,2,3-triazol-1-yl)butane; A=ClO(4)(-), BF(4)(-)) and Fe(x)Zn(1-x)(bbtr)(3)](ClO(4))(2) (0
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| Keywords: | iron magnetic properties N ligands phase transitions spin crossover |
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