Cyclopentadienyl derivatives of magnesium and sodium in cross-combination reaction with allyl compounds catalyzed by Pd complexes |
| |
| Authors: | U. M. Dzhemilev A. G. Ibragimov E. V. Gribanova L. M. Khalilov |
| |
| Affiliation: | (1) Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa |
| |
| Abstract: | Conclusions An effective method was developed for synthesizing allylcyclopentadienes by cross-combination of cyclopentadienyl derivatives of magnesium and sodium with O-, N-, and C-containing allyl compounds in the presence of palladium complexes. The substituted cyclopentadienes obtained comprise equilibrium mixtures of isomers, containing 1- and 2-allylcyclopentadienes in a 1 :1 ratio.Translated from Izvestiya AkademiiNauk SSSR, Seriya Khimicheskaya,. No. 11, pp. 2562–2566, November, 1985. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
