Platinum(IV) oxide catalyzed H-D exchange reactions in arylsilanes |
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| Authors: | Yamamoto Mitsuru Oshima Koichiro Matsubara Seijiro |
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| Affiliation: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoudai-katsura, Nishikyo, Kyoto 615-8510, Japan. |
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| Abstract: | [reaction: see text] Arylsilanes were regioselectively labeled with deuterium by treatment with platinum(IV) oxide and deuterium oxide under hydrothermal conditions. Arylsilanols were also labeled with regioselectively under the same conditions. |
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