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Kinetic Analysis of the Thermal Decomposition of Dialkyldithiocarbamates Chelates of Indium(III)
Authors:Souza  A G  Oliveira  M M  Santos  I M G  Conceição  M M  Nunes  L M  Machado  J C
Institution:1.Departamento de Química, CCEN, Universidade Federal da Paraíba, 58059-900, cJo?o Pessoa, Paraíba, Brazil
;2.Departamento de Química, Universidade Federal de Minas Gerais, 31.270-901, Belo Horizonte, Minas Gerais, Brazil
;
Abstract:The kinetics of thermal decomposition of solid In(S2CNR2)3 complexes, (R=CH3, C2H5, n-C3H7,i-C3H7, n-C4H9 and i-C4H9), has been studied using isothermal and non-isothermal thermogravimetry. Superimposed TG/DTG/DSC curves show that thermal decomposition reactions occur in the liquid phase, except for the In(S2CNMe2)3 and In(S2CNPri 2)3 compounds. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:dialkyldithiocarbamates  indium  kinetics  thermogravimetry
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