Concise enantioselective synthesis of furocaulerpin |
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| Affiliation: | 1. ETH Zürich, Department of Chemistry and Applied Biosciences, Laboratory of Inorganic Chemistry, Vladimir-Prelog Weg 1, 8093 Zürich, Switzerland;2. Eawag, Swiss Federal Institute of Aquatic Science and Technology, Überlandstrasse 133, CH-8600 Dübendorf, Switzerland |
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| Abstract: | The first total synthesis of both enantiomers of furocaulerpin was accomplished in good yields with a high control of the stereogenic center by enzymatic resolution, a total control of the configuration of the central double bond and the construction of the dienyne moiety via a Stille cross-coupling. |
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