Solid + liquid equilibria of (n-alkane + cyclohexane) mixtures at high pressures

Solid+liquid equilibria (SLE) of n-alkanes (tridecane, hexadecane, octadecane, or eicosane) + cyclohexane] at very high pressures up to about 1.0 GPa have been investigated in the temperature range from 293 to 363 K using a thermostated apparatus for the measurements of transition pressures from the liquid to the solid state in two component isothermal solutions. The freezing temperature of each mixture increases monotonously with increasing pressure. The eutectic point of the binary systems shifts to a higher temperature and to a higher n-alkane concentration with increasing pressure. The pressure–temperature–composition relation of the high-pressure solid–liquid equilibria, a polynomial based on the general solubility equation at atmospheric pressure, was satisfactorily used. Additionally, the SLE of the binary system (tridecane+cyclohexane) at normal pressure was measured by the dynamic method. The results at high pressure for all systems were compared to that at normal pressure.