Palladium nanoparticles supported on a poly(N-vinyl-2-pyrrolidone)-modified mesoporous carbon nanocage as a novel heterogeneous catalyst for the Heck reaction in water |
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| Authors: | Roozbeh Javad Kalbasi Neda MosaddeghAlireza Abbaspourrad |
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| Affiliation: | a Department of Chemistry, Shahreza Branch, Islamic Azad University, 311-86145 Shahreza, Isfahan, Iran
b School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, United States |
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| Abstract: | Palladium nanoparticles supported on poly(N-vinyl-2-pyrrolidone)/CKT-3 (a mesoporous carbon nanocage) were employed effectively as novel heterogeneous catalyst for the Heck coupling reaction. The results showed that aryl halides (-Cl, -Br, -I) underwent coupling with a variety of alkenes at 60 °C in water under aerobic conditions. The very stable nanocomposite catalyst was easily recovered, showed negligible Pd leaching, and retained good activity for at least ten successive runs without any additional activation. |
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| Keywords: | Heck reaction Mesoporous carbon nanocage Pd nanoparticles Water |
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