| 赤霉酸甲酯及其类似物的2D NMR研究 |
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| 引用本文： | 崔育新 李宇. 赤霉酸甲酯及其类似物的2D NMR研究[J]. 波谱学杂志, 1993, 10(1): 61-67 |
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| 作者姓名： | 崔育新 李宇 |
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| 作者单位： | 兰州大学应用有机化学国家重点实验室, 兰州大学应用有机化学国家重点实验室, 兰州 730000 |
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| 摘 要： | 应用1H-1H COSY,NOESY,13C-1H COSY等2DNMR和DEPT技术,完成了赤霉酸甲酯(2),13-O-乙酰基赤霉素甲酯(3)及其3位差向异构体(4)的1H和13CNMR化学位移的全指定,并探讨了它们的相对构型,相关质子间的偶合常数也支持所得结果。
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| 关 键 词： | 2D NMR 化学位移 赤霉酸甲酯 差向异构体 构型 |
| 收稿时间： | 1992-05-16 |
2D NMR STUDIES ON METHYL GIBBERELLATE AND ITS ANALOGUES |
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| Cui Yuxin,Li Yu,Xie Wenge and Pan Xinfu. 2D NMR STUDIES ON METHYL GIBBERELLATE AND ITS ANALOGUES[J]. Chinese Journal of Magnetic Resonance, 1993, 10(1): 61-67 |
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| Authors: | Cui Yuxin Li Yu Xie Wenge Pan Xinfu |
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| Affiliation: | The State Key Laboratory of Applied Organic Chemistry Lanzhou University, The Institute of Organic Chemistry Lanzhou University, Lanzhou 730000 |
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| Abstract: | Gibberellins form an important group of plant growth hormone, which have many biological activities. Its structure was determined by X-ray single crystal diffraction, no complete assignment of 1H and 13C NMR spectrum of the compounds have been reported. In this paper, all the 1H and 13C NMR chemical shifts of methyl gibberellate (2), 13- acetoxygibberellin A1 methyl ester ( 3 ) and its 3-epimer (4) were assigned by 1H-1H COSY , 13C-1H COSY, NOESY and DEPT, and their relative configurations were discussed. |
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| Keywords: | Two-dimensional NMR Chemical shift Methyl gibbercllate Epimer Configuration . |
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