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Hydrangea-like ZnO nanospheres on Al substrates via hydrothermal synthesis for photocatalytic activity
Authors:Zhi Zeng  Shiyong Gao  Guangning Wang  Xinzhi Ma  Dandan Sang  Shujie Jiao  Dongbo Wang  Jie Jia  Gengxin Hu  Jinzhong Wang
Affiliation:1. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, China;2. Key Laboratory for Photonic and Electric Bandgap Materials Ministry of Education, Harbin Normal University, Harbin, China;3. School of Physical Science and Information Technology, Shandong Key Laboratory of Optical Communication Science and Technology, Liaocheng University, Liaocheng, China
Abstract:Hydrangea-like ZnO nanospheres were fabricated on Al substrates via a facile hydrothermal method with only one step. Scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and photoluminescence were used to investigate their morphology, component, structure, and optical properties. The hierarchical nanospheres are fabricated by 2D nanosheets with the shape of 3D sphere. By adjusting the reaction time, the formation process was monitored. The photocatalytic activity of ZnO nanospheres was also investigated for their dye degradation, and they exhibit good photocatalytic ability to congo red, with the degradation rate of 98.4%. Besides, they have universal catalysis effect on methyl orange.
Keywords:crystal growth  hydrothermal method  photocatalytic activity  plate assembly  ZnO nanosphere
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