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Dihydrophenazine-based double-anchoring dye for dye-sensitized solar cells
Authors:Dhirendra Kumar  Yu-Lin Chen  Chih-Hung Tsai  Ken-Tsung Wong
Institution:1. Department of Chemistry, National Taiwan University, Taipei, Taiwan;2. Department of Opto-Electronic Engineering, National Dong Hwa University, Hualien, Taiwan
Abstract:A novel dihydrophenazine-based organic di-anchoring dye DK-11 was synthesized by utilizing a simple synthetic protocol. The dye was characterized by optical and electrochemical studies and used as a sensitizer for dye-sensitized solar cell. The proposed butterfly structure was supported by IR experiments which ensured the binding of both carboxylic acid units on the semiconductor surface. Using the dye DK-11 , the device generated an efficiency of 5.07% with JSC, VOC, and FF values of 10.65 mA/cm2, 0.67 V, and 0.71, respectively.
Keywords:di-anchoring dyes  donor-acceptor dyes  dye-sensitized solar cells  dye-TiO2 binding  molecular geometry
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