首页 | 本学科首页   官方微博 | 高级检索  
     


Electronic absorption spectrum of Ba(MnO4)2·3H2O/Ba(ClO4)2·3H2O
Authors:L. W. Johnson and S. P. McGlynn
Affiliation:

Coates Chemical Laboratories, The Louisiana State University, Baton Rouge, Louisiana 70803, USA

Abstract:Polarized absorption spectra of Ba(MnO4)2·3H2O/Ba(ClO4)2·3H2O mixed single crystals are reported at 4.2°K. Previous 1T21A1 assignments for the 5200 Å and 3000 Å absorption bands of MnO4 are substantiated; further support is provided for the 1T11A1 assignment of the 3600 Å absorption band of MnO4. The site-splitting of the 5200 Å 1T2 state is E(1E)−E(1A) ≈ −150 cm−1; that of the 3000 Å 1T2 state is E(1E)−E(1A) ≈ 300 cm−1. A significant e vibronic intensity component is observed in the 5200 Å 1T2 state.
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号