Metallaborane reaction chemistry. A predicted and found tailored facile and reversible capture of SO2 by a B-frame-supported bimetallic: structures of [(PMe2Ph)2PtPd(phen)B10H10] and [(PMe2Ph)2Pt(SO2)Pd(phen)B10H10 |
| |
| Authors: | Bould Jonathan Kennedy John D |
| |
| Affiliation: | The School of Chemistry of the University of Leeds, UKLS2 9JT. jbould@gmail.com |
| |
| Abstract: | The formally closo twelve-vertex {ortho-M2B10} dimetallaborane system has been predictively tailored for reversible uptake of SO2 across the metal-metal bond, as exemplified by the formation of [(PMe2Ph)2Pt(SO2)Pd(phen)B10H10] from [(PMe2Ph)2PtPd(phen)B10H10]. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
