| 4-羟基-喹啉酸盐钴(II)配合物(英文) |
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| 引用本文： | 杨高文,袁荣鑫,黄雪峰. 4-羟基-喹啉酸盐钴(II)配合物(英文)[J]. 无机化学学报, 2005, 21(12) |
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| 作者姓名： | 杨高文 袁荣鑫 黄雪峰 |
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| 作者单位： | 1. 常熟理工学院,江苏省新型功能材料重点建设实验室,常熟,215500
2. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 江苏省新型功能材料重点建设实验室基金资助。 |
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| 摘 要： | C om pound1was afforded through hydrotherm altreatm ent of ethyl4-hydroxy3-quinolinecarboxylateand C oC l2in the presence of pyridine that prom oteshydrolysis of ethyl4-hydroxy-3-quinolinecarboxylate(hqs)(Schem e1).The coordination environm entaround cobalt center can be best described as aslightly distorted octahedron defined four oxygenatom s from tw o ligand hqs and two nitrogen atom sfrom two pyridines(Fig.1).phenolate and one of oxy-gen of carboxylic group of the sam e organic ligand hqc…
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| 关 键 词： | 6-甲基-4-羟基-喹啉酸盐 钴 水热法 晶体结构 |
Bis(4-hydroxy-3-quinolinecarboxylate) Bipyridine Cobalt(Ⅱ) |
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| YANG Gao-Wen,YUAN Rong-Xin,HUANG Xue-Feng. Bis(4-hydroxy-3-quinolinecarboxylate) Bipyridine Cobalt(Ⅱ)[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(12) |
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| Authors: | YANG Gao-Wen YUAN Rong-Xin HUANG Xue-Feng |
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| Affiliation: | YANG Gao-Wen1 YUAN Rong-Xin1 HUANG Xue-Feng*,2 |
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| Abstract: | The geometry around Co center in bis(4-hydroxy-3-quinolinecarboxylate) bipyridine cobalt(II) (1) , prepared by the hydrothermal treatment of ethyl 4-hydroxy-3-quinolinecarboxylate and CoCl2 in the presence of pyridine, displays a slightly distorted octahedron in which two apical positions are occupied by py and equatorial plane is composed of four O atoms from two hydroxy and carboxylate groups. CCDC: 285591. |
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| Keywords: | 6-methyl-4-hydroxy-3-quinolinecarboxylate cobalt hydrothermal crystal structure |
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