Coupling reaction of alkyl chlorides with silyl enolates catalyzed by indium trihalide |
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| Authors: | Nishimoto Yoshihiro Yasuda Makoto Baba Akio |
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| Affiliation: | Department of Applied Chemistry, Center for Atomic and Molecular Technologies (CAMT), Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. |
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| Abstract: | Indium(III) halide catalyzed not only the coupling of alkyl chlorides with silyl enolates derived from esters, ketones, and aldehydes to give a variety of alpha-alkylated carbonyl compounds but also one-pot, three-component reactions of aldehyde enolate, alkyl chloride, and allylsilane or alkynylsilane. |
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