Cubane derivatives |
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| Authors: | D S Yufit Yu T Struchkov L T Eremenko |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(2) Institute of Chemical Physics, Russian Academy of Sciences, 142432 Chemogolovka, Russian Federation |
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| Abstract: | A precision X-ray structural investigation of 1,4-dimethoxycarbonylcubane at 218 K was carried out. Analysis of the experimental maps of deformational electron density indicates the existence of partial electron density transfer from the cage bonds to the Ccubane-COOR bonds and the shift of the electron density to the symmetrical (relative to the COOMe planes) cube faces.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1210–1213, July, 1993. |
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| Keywords: | 1 4-dimethoxycarbonylcubane X-ray structural analysis electron density distribution |
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