| 接枝物EVA-g-PBMA的合成及表征 |
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| 引用本文： | 石旭华,陈汉佳,欧阳效敏.接枝物EVA-g-PBMA的合成及表征[J].化学研究与应用,2005,17(3):339-342. |
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| 作者姓名： | 石旭华 陈汉佳 欧阳效敏 |
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| 作者单位： | 汕头大学化学系,广东,汕头,515063;汕头大学化学系,广东,汕头,515063;汕头大学化学系,广东,汕头,515063 |
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| 摘 要： | 本文合成了具有端羟基的聚甲基丙烯酸丁酯(PBMA-OH)，并通过与MA反应，实现了端羟基转化，为接枝EVA水解产物起到了“搭桥”的作用。通过H^1 NMR对不同水解度的EVA皂化产物进行了序列结构剖析，并合成了新型接枝物EVA-g-PBMA。
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| 关 键 词： | 端羟基PBMA 乙烯-醋酸乙烯酯树脂 接枝聚合物 核磁共振谱 |
| 文章编号： | 1004-1656(2005)03-0339-04 |
| 修稿时间： | 2004年9月13日 |
Preparation and characterization of grafted polymer EVA-g-PBMA |
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| SHI Xu-hua,CHEN Han-jia,OUYANG Xiao min.Preparation and characterization of grafted polymer EVA-g-PBMA[J].Chemical Research and Application,2005,17(3):339-342. |
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| Authors: | SHI Xu-hua CHEN Han-jia OUYANG Xiao min |
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| Abstract: | Hydroxyl-terminated PBMA was synthesized successfully by adding chain transfer agents of mercaptoethanol(TEG).In order to be grafted on EVA-OH,carboxyl-terminated PBMA was prepared by reacting the hydroxyl-terminated PBMA with maleic anhydride.The microstructures of the saponified EVA were studied by H~1NMR.The newly grafted polymer of EVA-g-PBMA was also synthesized and characterized by means of IR. |
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| Keywords: | hydroxyl-terminated PBMA EVA grafted polymer NMR |
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