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Synthesis of some new derivatives of dithiene-and oxathienecarboxylic acids
Authors:V. A. Mamedov  F. G. Sibgatullina  V. P. Gubskaya  R. M. Gainullin  R. R. Shagidullin  A. V. Il'yasov
Abstract:Substituted anilides of 1,4-dithiene- and oxathienecarboxylic acids were synthesized. It was shown that the reaction of 3-phenyl-1,4-dithi-2-ene-2-carboxyl chloride with 2-aminopyridines, depending on the base used and the reaction conditions, leads to the formation of N-[3prime-phenyl-2prime-(1prime,4prime-dithi-2prime-en)ylcarbonyl]2-amino-pyridine and/or N,Nprime-bis[3-phenyl-2-(1,4-dithi-2-en)-ylcarbonyl]pyridonimine. The data of IR, UV, and PME spectroscopy were used to confirm the structure of the synthesized compounds.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Science Center, Russian Academy of Sciences. Kazan 420083. Translated fro, Khimiya Geterotskiklicheskikh Soedinenii, No. 9, pp. 1191–1196, September, 1994. Original article submitted May 10, 1994.
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