| 高热稳定性氟化聚醚砜的合成及其在阵列波导光栅复用器中的应用 |
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| 引用本文： | 王菲,李艾泽,孙伟,赵禹,张大明,姜振华,刘式墉. 高热稳定性氟化聚醚砜的合成及其在阵列波导光栅复用器中的应用[J]. 高等学校化学学报, 2004, 25(9): 1736-1739 |
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| 作者姓名： | 王菲 李艾泽 孙伟 赵禹 张大明 姜振华 刘式墉 |
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| 作者单位： | 1. 集成光电子学国家重点联合实验室吉林大学实验区, 长春130023;2. 吉林大学化学学院, 长春130023 |
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| 基金项目： | 国家重点基础研究发展规划项目 (批准号 :TG2 0 0 0 0 3 660 2 )，国家高技术研究发展计划 (批准号 :2 0 0 1AA 3 12 160 )资助 |
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| 摘 要： | 用合成的3-三氟甲基苯侧基聚醚砜(3F-PES)作为波导芯层材料制作了新型硅基聚合物阵列波导光栅(AWG)复用器.采用DSC,TGA和AFM等方法对3F-PES的光学性质和热稳定性进行了表征.DSC和TGA结果显示,3F-PES的玻璃化转变温度为170℃,在空气中5%的热失重温度为542℃,表明具有非常好的热稳定性.3F-PES溶液在旋涂时具有很好的成膜性,AFM照片显示,粗糙度起伏为0.35nm.近红外吸收谱表明,3F-PES在光通讯波段有较小的吸收,适合用来制作低损耗的光波导器件.用3F-PES作为波导芯层材料制作的八通道硅基聚合物阵列波导光栅(AWG)复用器的通道间隔为1.603nm,中心波长为1550.15nm.
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| 关 键 词： | 波分复用 阵列波导光栅 氟化聚醚砜 |
| 文章编号： | 0251-0790(2004)09-1736-04 |
| 收稿时间： | 2003-12-19 |
Synthesis of Fluorinated Poly(ether sulfone) with High Thermal Stability and Its Application for Arrayed Waveguide Grating Multiplexer |
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| WANG Fei,LI Ai-Ze,SUN Wei,ZHAO Yu,ZHANG Da-Ming ,JIANG Zhen-Hua,LIU Shi-Yong. Synthesis of Fluorinated Poly(ether sulfone) with High Thermal Stability and Its Application for Arrayed Waveguide Grating Multiplexer[J]. Chemical Research In Chinese Universities, 2004, 25(9): 1736-1739 |
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| Authors: | WANG Fei LI Ai-Ze SUN Wei ZHAO Yu ZHANG Da-Ming JIANG Zhen-Hua LIU Shi-Yong |
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| Affiliation: | 1. State Key Laboratory on Integrated Optoelectronics, Jilin University Region, Changchun 130023, China;2. College of Chemistry, Jilin University, Changchun 130023, China |
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| Abstract: | A new arrayed waveguide grating(AWG) multiplexer was fabricated by using synthesized 3F-PES as the waveguide core. The DSC and TGA exhibit T g and the temperature at which 5% mass loss occurred in air of 3F-PES are 170 and 542℃, respectively. The infrared absorption spectrum indicates that 3F-PES has a high optical transparency in the infrared communication region. The AFM exhibits the roughness of the 3F-PES film is 0.35 nm. The arrayed waveguide grating(AWG) multiplexer was fabricated by using the 3F-PES as the waveguide core. The AWG multiplexer exhibits a wavelength channel spacing of 1.603 nm and a center wavelength of 1 550.15 nm. |
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| Keywords: | Wavelength division multiplexing Arrayed waveguide grating Fluorinated poly(ether sulfone) |
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