| 电荷转移复合物在反应中作用的研究进展 |
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| 引用本文： | 刘英进,山本峻三,末石芳巳. 电荷转移复合物在反应中作用的研究进展[J]. 化学研究与应用, 2000, 12(5): 491-497 |
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| 作者姓名： | 刘英进 山本峻三 末石芳巳 |
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| 作者单位： | テ700-8530日本国冈山市冈山大学理学部化学科 |
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| 摘 要： | 总结了存在电荷转移复合物反应的反应历程的研究结果，在Ｄｉｅｌｓ－Ａｌｄｅｒ反应和氢负离子转移反应中观测到负的表观活化焓，表明电荷转移复合物是真正的反应中间体。
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| 关 键 词： | 电荷转移复合物 中间体 Diels－Alder反应 |
| 修稿时间： | 2000-07-19 |
RESEARCH PROGRESS ON THE ACTION OF CHARGE-TRANSFER COMPLEXES IN THE REACTIONS |
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| LIU Ying-jin,Shunzo Yamamoto,Yoshimi Sueishi. RESEARCH PROGRESS ON THE ACTION OF CHARGE-TRANSFER COMPLEXES IN THE REACTIONS[J]. Chemical Research and Application, 2000, 12(5): 491-497 |
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| Authors: | LIU Ying-jin Shunzo Yamamoto Yoshimi Sueishi |
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| Abstract: | Charge transfer (CT) complexes formed between electron donors and acceptors have been studied extensively.It has been considered impossible to distinguish kinetically whether CT compleses are real intermediates in the reactions so far.This review summarizes the results of CT complexes studies with focusing on the mechanistic aspects.Negative observed activation enthalpies obtained in hydride transfer reactions and in Diels Alder reactions indicate that CT complexes act as true intermediates in these reactions. |
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| Keywords: | charge transfer complex intermediates Diels Alder reaction hydride transfer reaction |
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