Efficient dye regeneration in solid-state dye-sensitized solar cells fabricated with melt processed hole conductors |
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Authors: | Mindaugas JuozapaviciusBrian C O’Regan Assaf Y AndersonJuozas V Grazulevicius Viktorija Mimaite |
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Institution: | a Department of Chemistry, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdom b Department of Organic Technology, Kaunas University of Technology, Radvilenu plentas 19, LT50254 Kaunas, Lithuania |
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Abstract: | A new method for melting hole transporting materials (HTM) into mesoporous TiO2 electrodes to obtain solid-state dye-sensitized solar cells (DSSC) is reported. Internal coverage is determined from the efficiency of hole conductor oxidation by photo-oxidized dyes (dye regeneration), measured using transient absorption spectroscopy. High efficiency regeneration indicates complete coverage of the electrode internal surface. A high work function hole conductor (>5.2 eV) was found to give shorter regeneration lifetimes (<1 μs) and better regeneration efficiencies (>90%) than expected. Cell photocurrents were low, but improved after iodine vapor doping of the hole conductor. Counter intuitively, doping also reduced the recombination rate constant 7-fold. A solid state solar cell with power conversion efficiency of 0.075% at 1 sun is reported. |
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Keywords: | Dye-sensitized solar cell Melt-processable Organic hole transporting material Transient absorption spectroscopy |
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