Molecular tectonics: design of enantiomerically pure helical tubular crystals with controlled channel size and orientation |
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Authors: | Lin Mei-Jin Jouaiti Abdelaziz Grosshans Philippe Kyritsakas Nathalie Hosseini Mir Wais |
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Institution: | Laboratoire de Chimie de Coordination Organique (UMR CNRS-UDS 7140), Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, 67000 Strasbourg, France. |
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Abstract: | The combination of four enantiomerically pure organic tectons composed of a rigid chiral backbone bearing two terminal pyridyl coordinating sites with ZnSiF(6) behaving as an infinite pillar leads to the formation of tubular 2-D enantiomerically pure helical channels with controlled size and orientation. |
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