2,2'-Bipyridinyl carboranes as B,N,N-ligands in cyclometallated complexes of platinum(II) |
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| Authors: | Prokhorov Anton M Slepukhin Pavel A Rusinov Vladimir L Kalinin Valery N Kozhevnikov Dmitry N |
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| Institution: | Ural Federal University, Mira 28, Ekaterinburg, Russia. aprohor@yandex.ru |
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| Abstract: | Novel B,N,N-cyclometallated Pt(II) complexes of 2,2'-bipyridin-6-yl carboranes exhibit absorption and emission similar to relative Pt(II) complexes of aromatic C,N,N-ligands: the same transitions but lower intensities. DFT calculations suggest the former emits from the (3)MLCT state while for the latter the mixed (3)ICT-MLCT transitions should be considered. |
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