Reactions of ruthenium and osmium cluster carbonyls with heteroatom-substituted and functionalized alkynes |
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Authors: | A A Koridze |
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Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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Abstract: | The results of studies of the reactions of ruthenium and osmium cluster carbonyls with metal alkynes, silylalkynes, propargyl
alcohols and their derivatives, diynes, enynes, and ferrocenylacetylene are summarized. Intramolecular rearrangements in the
cluster complexes including migrations of carbonyl, hydride, and hydrocarbon ligands as well as the metal core reorganization
are considered.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 1–17, January, 2000. |
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Keywords: | ruthenium carbonyl clusters osmium carbonyl clusters alkyne derivatives intramolecular rearrangements |
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