Chiral monophosphites derived from carbohydrate: conformational effect in catalytic asymmetric hydrogenation |
| |
| Authors: | Huang Hanmin Zheng Zhuo Luo Huili Bai Changmin Hu Xinquan Chen Huilin |
| |
| Institution: | Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, PR China. |
| |
| Abstract: | reaction: see text]. The carbohydrate-derived chiral monophosphites with additional groups have been synthesized and used for asymmetric hydrogenation of dimethyl itaconate and enamides. Up to 99.6% ee and 98.5% ee have been obtained, respectively. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
