| 中性载体阳离子电极膜电化学的计算机数字模拟 |
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| 引用本文： | 王柯敏 霍希琴. 中性载体阳离子电极膜电化学的计算机数字模拟[J]. 高等学校化学学报, 1994, 15(11): 1602-1606 |
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| 作者姓名： | 王柯敏 霍希琴 |
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| 作者单位： | 湖南大学化学化工系, 长沙, 410082 |
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| 摘 要： | 对中性载体阳离子电极膜3种可能的传输模式进行了数字模拟,研究了淌度、浓度、配合物稳定常数以及阴离子亲脂性对电极电位响应的影响。模拟结果对于廓清这类电极响应机理,解释有关实验现象及指导新电极设计提供了有用的信息。
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| 关 键 词： | 中性载体 离子电极 传输模式 数字模拟 |
| 收稿时间： | 1994-02-26 |
Digital Simulation of Neutral Carrier Cation Selective Electrode Membrane Electrochemical Properties |
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| WANG Ke-Min,HUO Xi-Qin,YU Ru-Qin. Digital Simulation of Neutral Carrier Cation Selective Electrode Membrane Electrochemical Properties[J]. Chemical Research In Chinese Universities, 1994, 15(11): 1602-1606 |
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| Authors: | WANG Ke-Min HUO Xi-Qin YU Ru-Qin |
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| Affiliation: | Department of Chemistry and Chemical Enginnering, Hunan University, Changsha, 410082 |
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| Abstract: | Digital simulation techniques are applied to investigate the electrochemical properties of neutral carrier cation selective electrode membranes with a particular attention bening paid to three possible transport mechnisms. The effects of mobilities, concentrations,complex formation constants and hydrophilic anions on potention response are studied.The simulation results provide useful information for exploring the response mechanism of this type of electroded,explaining some experimental phenomena and designing new neutral carrier electrodes. |
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| Keywords: | Neutral carrier Ion electrode Transport mechanism Digital simulation |
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