| 以1,4-二硝基苯甲酸及邻菲咯啉为配位的镧系金属配位聚合物的合成、结构及性质研究 |
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| 引用本文： | 于美慧,胡明,冯占宇,薛丰.以1,4-二硝基苯甲酸及邻菲咯啉为配位的镧系金属配位聚合物的合成、结构及性质研究[J].无机化学学报,2014,30(6):1261-1266. |
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| 作者姓名： | 于美慧 胡明 冯占宇 薛丰 |
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| 作者单位： | 内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021;内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021;内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021;内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021 |
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| 基金项目： | 国家自然科学基金(No.21361017)；内蒙古自然科学基金(No.2012MS0214)；内蒙古高等学校科学技术研究重点研究(No.NJZZ12012)资助项目。 |
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| 摘 要： | 以1,4-二硝基苯甲酸(HL)和1,10-邻菲咯啉(phen)为配体,通过水热法与镧系金属盐合成了7个一维链状配位聚合物,其分子式为Ce2L6(phen)2]n(1)和LnL3phen]n(Ln=Sm,2;Eu,3;Gd,4;Tb,5;Dy,6;Er,7)。由X-射线单晶衍射测定了化合物晶体结构,通过磁性以及荧光测试表征了部分化合物的磁性和荧光性质。
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| 关 键 词： | 1 4-二硝基苯甲酸 1 10-邻菲咯啉 晶体结构 荧光 磁性 |
| 收稿时间： | 2013/8/20 0:00:00 |
| 修稿时间： | 2014/3/27 0:00:00 |
Syntheses, Crystal Structures and Properties of Lanthanide Coordination Polymers Based on 2, 4-Dinitro-benzoic Acid and 1, 10-Phenanthroline |
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| YU Mei-Hui,HU Ming,FENG Zhan-Yu and XUE Feng.Syntheses, Crystal Structures and Properties of Lanthanide Coordination Polymers Based on 2, 4-Dinitro-benzoic Acid and 1, 10-Phenanthroline[J].Chinese Journal of Inorganic Chemistry,2014,30(6):1261-1266. |
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| Authors: | YU Mei-Hui HU Ming FENG Zhan-Yu and XUE Feng |
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| Institution: | Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China;Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China;Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China;Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China |
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| Abstract: | Seven one-dimensional chain lanthanide coordination polymers based on 2,4-dinitro-benzoic acid (HL) and 1,10-phenanthroline (phen) as ligands were successfully synthesized with rare earth metal salts by hydrothermal method, namely, Ce2L6(phen)2]n (1) and LnL3phen]n (Ln=Sm, 2; Eu, 3; Gd, 4; Tb, 5; Dy, 6; Er, 7). The compounds have been structurally confirmed by single-crystal X-ray diffractions and characterized by magnetic and fluorescent properties. CCDC: 883735, 1; 946599, 2; 883736, 3; 883836, 4; 883837, 5; 883838, 6; 946598, 7. |
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| Keywords: | 2 4-dinitro-benzoic acid 1 10-phenanthroline crystal structure fluorescence magnetic property |
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