Influence of Temperature on Molecular Dipole Orientation in the Binary Mixture of Polar-Nonpolar Liquids

Abstract

The excess correlation factor in the binary mixture of polar liquid (i.e., i-butanol and t-butanol) in the nonpolar solvent (i.e., benzene, tetrachloromethane, n-heptane) has been evaluated at 301°K,307°K,313°K and 318°K. An extensive study has been made on the influence of temperature on the orientation of molecular dipoles in the solution with the help of the excess correlation factor.