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Analytic inhomogeneous electron liquid and its density for model spin-compensated two-electron atomic ions with Coulomb confinement: an exact nonrelativistic Hamiltonian
Abstract:In earlier work, Howard and March (HM) proposed an analytic ground-state electron density ρ( r ) starting from the s-wave model of the He atom. Subsequently Ancarani has constructed by numerical methods a variational approach for this s-wave model with a lower energy than the HM result. This clearly means that the HM ρ( r ) is not the ground-state electron density of the He s-wave model. Therefore, we derive here an exact nonrelativistic Hamiltonian, with strong radial correlation plus Coulomb confinement, for which the HM ρ( r ) is indeed the ground-state electron density.
Keywords:Inhomogeneous electron liquids  Two-electron model atoms  Radial correlation  Exact Hamiltonian
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