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Short range order in molten Al–Si alloys
Abstract:We have studied the microscopic structure such as, concentration fluctuation in long wavelength limit (SCC(0)), Warren–Cowely short range order parameter (α 1), ratio of mutual and intrinsic diffusion coefficients (D M/D id) of molten Al–Si alloy at 1700?K using a statistical model of complex formation on the basis of quasi-lattice theory for weakly interacting systems. The approach used in this article reveals that molten Al–Si alloy at 1700?K is a weakly interacting heterocoordinating system and the alloy is more ordered in the Al-rich end.
Keywords:Al–Si liquid alloys  microscopic structure  quasi-lattice theory  diffusion coefficients
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