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Thermodynamic Properties of Multicomponent Liquid Mixtures
Abstract:Considering a ternary liquid mixture to be made up of three binary mixtures, by means of cell model using Sutherland type potential function for pair interaction between molecules, a statistical theory for binary liquid mixtures has been extended for ternary systems. In the light of above extension, excess volume ( V E ), excess energy ( E E ) and excess entropy ( TS E ) have been computed for three binary (benzene + cyclohexane, benzene + chlorobenzene and cyclohexane + chlorobenzene) and the resultant ternary system (benzene + cyclohexane + chlorobenzene) at 298.15 K. All the above mentioned excess properties have been computed from the data of ultrasonic velocity and density only.
Keywords:Excess Volume  Excess Energy  Excess Entropy  Ternary Mixture
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