Preconcentration neutron activation analysis of lanthanides by cloud point extraction using PAN |
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Authors: | A. Pérez-Gramatges A. Chatt |
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Affiliation: | (1) Trace Analysis Research Centre, Department of Chemistry, Dalhousie University; Instituto Superior de Tecnologías y Ciencias Aplicadas, Halifax, NS, B3H 4J3 Canada; Havana, A.P. 6163 Cuba;(2) Instituto Superior de Tecnologías y Ciencias Aplicadas, Havana, A.P. 6163 Cuba |
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Abstract: | Summary Methods for the simultaneous preconcentration of lanthanides by cloud point extraction and their determination using neutron activation analysis have been developed. The preconcentration method involves the use of a nonionic surfactant and a chelating agent. A fairly small volume of surfactant-rich phase was obtained under optimized experimental conditions, leading to detection limits between 0.3 and 3.0 ng . g-1. Critical parameters that influence extraction efficiency were solution pH and concentration of chelating agent, and to a lesser extent, ionic strength and temperature. Most of the chelates were quantitatively extracted (>90%) at high pH values. Selective separation can be achieved by varying some of the experimental conditions. |
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