Replacing the hydrogen in the intermolecular hydrogen bond of the cyanuric acid-bipyridyl adduct by Ag(I) |
| |
| Authors: | K Sivashankar Anupama Ranganathan and V R Pedireddi |
| |
| Institution: | (1) Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, 560 064 Jakkur PO, Bangalore, India;(2) Present address: Division of Organic Chemistry, National Chemical Laboratory, 411 008 Pune, India |
| |
| Abstract: | A complex between cyanuric acid (CA), 4,4′-bipyridyl (BP) and Ag(I), with the composition, Ag2(C3H2N3O3-κN)2 (C10H8N2-κN)] has been prepared. Crystal structure analysis shows that it has a chain structure in which the CA molecules are linked
to the BP units through silver atoms by the formation of N-Ag-N bonds, wherein one of the hydrogens of CA is replaced by Ag(I),
showing thereby the chains connected to one another by N-H...O hydrogen bonds formed between the CA molecules. This intermolecular
chain structure resembles the chain structure of the CA.BP adduct where CA-BP-CA chains formed by N-H...N hydrogen bonds are
linked to one another by N-H...O hydrogen bonds between the CA molecules. |
| |
| Keywords: | Cyanuric acid-Ag-4 4’ -bipyridyl adduct N-Ag-N chains crystal structure analysis |
| 本文献已被 SpringerLink 等数据库收录！ |
|
