A voltammetric study of direct electron transfer to cytochrome c using a very large assembly of carbon microelectrodes |
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Authors: | Kudera M Nakagawa Y Fletcher S Hill H A |
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Institution: | Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UKOX1 3QR. |
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Abstract: | A very large assembly of more than 8000 carbon fibre microdisk electrodes was used to study direct electron transfer to cytochrome c. Near steady-state cyclic voltammograms were observed, which exhibited excellent signal-to-noise ratios despite the low concentrations of cytochrome c employed (1-50 microM). The high resolution of the voltammograms allowed the formal potential of the native form of cytochrome c to be determined over a range of solution pH. |
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